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Humboldt-Universität zu Berlin - Mathematisch-Naturwissen­schaft­liche Fakultät - SFB 951 - HIOS

A8
Adjusting energy levels of hybrid inorganic/organic heterostructures

Publications

S. Park, T. Schultz, X. Xu, B. Wegner, A. Aljarb, A. Han, L.-J. Li, V. C. Tung, P. Amsalem, N. Koch
Demonstration of the key substrate-dependent charge transfer mechanisms between monolayer MoS2 and molecular dopants
Communications Physics 2, 109 (2019)
doi: 10.1038/s42005-019-0212-y
Q. Wang, V. Diez-Cabanes, S. Dell'Elce, A. Liscio, B. Kobin, H. Li, J-L. Brédas, S. Hecht, V. Palermo, E. J.W. List-Kratochvil, J. Cornil, N. Koch, G. Ligorio
Dynamically switching the surface electronic and electrostatic properties of indium-tin oxide electrodes with photochromic monolayers: Toward photoswitchable optoelectronic devices
ACS Appl. Nano Mater. 2, 074001 (2019)
doi: 10.1021/acsanm.9b00094
R. Schlesinger, F. Bussolotti, J. Yang, S. Sadofev, A. Vollmer, S. Blumstengel, S. Kera, N. Ueno, N. Koch
Gap states induce soft Fermi level pinning upon charge transfer at ZnO/molecular acceptor interfaces
Phys. Rev. Materials 3, 074601 (2019)
doi: 10.1103/PhysRevMaterials.3.074601
R. Schlesinger, S. Winkler, M. Brandt, S. Blumstengel, R. Ovsyannikov, A. Vollmerband, N. Koch
Energy level alignment at organic/inorganic semiconductor heterojunctions: Fermi level pinning at the molecular interlayer with a reduced energy gap
Phys. Chem. Chem. Phys. 21, 15072 (2019)
doi: 10.1039/C9CP02763G
H. Wang, S. V. Levchenko, T. Schultz, N. Koch, M. Scheffler, M. Rossi
Modulation of the work function by the atomic structure of strong organic electron acceptors on H‐Si(111)
Adv. Electron. Mater. 5, 1800891 (2019)
doi: 10.1002/aelm.201800891
F. Zu, C. M. Wolff, M. Ralaiarisoa, P. Amsalem, D. Neher, N. Koch
Unraveling the Electronic Properties of Lead Halide Perovskites with Surface Photovoltage in Photoemission Studies
ACS Appl. Mater. Interfaces 11, 21578 (2019)
doi: 10.1021/acsami.9b05293
N. Mutz, T. Meisel, H. Kirmse, S. Park, E. List-Kratochvil, N. Koch, C. T. Koch, S. Blumstengel, S. Sadofev
Pulsed thermal deposition of binary and ternary transition metal dichalcogenide monolayers and heterostructures
Appl. Phys. Lett. 114, 162101 (2019)
doi: 10.1063/1.5088758
S. Park, T. Schultz, A. Han, A. Aljarb, X. Xu, P. Beyer, A. Opitz, R. Ovsyannikov, L.-J. Li, M. Meissner, T. Yamaguchi, S. Kera, P. Amsalem, N. Koch
Electronic band dispersion determination in azimuthally disordered transition-metal dichalcogenide monolayers
Commun. Phys. 2 (2019)
doi: 10.1038/s42005-019-0166-0
T. Schultz, P. Amsalem, N. B. Kotadiya, T. Lenz, P. W. M. Blom, N. Koch
Importance of substrate work function homogeneity for reliable ionization energy determination by photoelectron spectroscopy
Phys. Status Solidi B 256, 1800299 (2019)
doi: 10.1002/pssb.2018002991
P. Beyer, D. Pham, C. Peter, N. Koch, E. Meister, W. Brütting, L. Grubert, S. Hecht, D. Nabok, C. Cocchi, C. Draxl, A. Opitz
State-of-matter-dependent charge-transfer interactions between planar molecules for doping applications
Chem. Mater. 31, 1237 (2019)
doi: 10.1021/acs.chemmater.8b01447
F. Zu, P. Amsalem, D. A. Egger, R. Wang, C. M. Wolff, H. Fang, M. A. Loi, D. Neher, L. Kronik, S. Duhm, N. Koch
Constructing the Electronic Structure of CH3NH3PbI3 and CH3NH3PbBr3 Perovskite Thin Films from Single-Crystal Band Structure Measurements
J. Phys. Chem. Lett. 10, 601 (2019)
doi: 10.1021/acs.jpclett.8b03728
Q. Wang, V. Diez-Cabanes, S. Dell’Elce, A. Liscio, B. Kobin, H. Li, J.-L. Brédas, S. Hecht, V. Palermo, E. J. W. List-Kratochvil, J. Cornil, N. Koch, G. Ligorio
Dynamically switching the electronic and electrostatic properties of Indium–Tin oxide electrodes with photochromic monolayers: Toward photoswitchable optoelectronic devices
ACS Appl. Nano Mater. 2, 1102 (2019)
doi: 10.1021/acsanm.9b00094
M. Kneiß, A. Hassa, D. Splith, C. Sturm, H. von Wenckstern, T. Schultz, N. Koch, M. Lorenz, M. Grundmann
Tin-assisted heteroepitaxial PLD-growth of κ -Ga2O3 thin films with high crystalline quality
APL Mater. 7, 022516 (2019)
doi: 10.1063/1.5054378
U. Hörmann, S. Zeiske, S. Park, T. Schultz, S. Kickhöfel, U. Scherf, S. Blumstengel, N. Koch, D. Neher
Direct observation of state-filling at hybrid tin oxide/organic interfaces
Appl. Phys. Lett. 114, 183301 (2019)
doi: 10.1063/1.5082704
M. Selig, E. Malic, K. J. Ahn, N. Koch, A. Knorr
Theory of optically induced Förster coupling in van der Waals coupled heterostructures
Phys. Rev. B 99, 035420 (2019)
doi: 10.1103/PhysRevB.99.035420
P. Caprioglio, F. Zu, C. M. Wolff, J. A. Márquez Prieto, M. Stolterfoht, N. Koch, T. Unold, B. Rech, S. Albrecht, D. Neher
High open circuit voltages in pin-type perovskite solar cells through strontium addition
Sustainable Energy Fuels 3, 550 (2019)
doi: 10.1039/c8se00509e
T. Schultz, N. C. Frey, K. Hantanasirisakul, S. Park, S. J. May, V. B. Shenoy, Y. Gogotsi, N. Koch
Surface termination dependent work function and electronic properties of Ti3C2Tx MXene
Chem. Mater., Article ASAP (2019)
doi: 10.1021/acs.chemmater.9b00414
M. H. Futscher, T. Schultz, J. Frisch, M. Ralaiarisoa, E. Metwalli, M. V. Nardi, P. Müller-Buschbaum, N. Koch
Electronic properties of hybrid organic/ inorganic semiconductor pn-junctions
J. Phys. Condens. Matter 31, 064002 (2019)
doi: 10.1088/1361-648X/aaf310
Rongbin Wang T. Katase, K.‐K. Fu, T. Zhai, J.Yang, Q. Wang, H. Ohta, N. Koch, S. Duhm
Oxygen Vacancies Allow Tuning the Work Function of Vanadium Dioxide
Adv. Mater. Interfaces 5, 1801033 (2018)
doi: 10.1002/admi.201801033
U. Hörmann, S. Zeiske, F. Piersimoni, L. Hoffmann, R. Schlesinger, N. Koch, T. Riedl, D. Andrienko, D. Neher
Stark effect of hybrid charge transfer states at planar ZnO/organic interfaces
Phys. Rev. B 98, 155312 (2018)
doi: 10.1103/PhysRevB.98.155312
J. Niederhausen, Y. Zhang, F. Cheenicode Kabeer, Y. Garmshausen, B. M. Schmidt, Y. Li, K.-F. Braun, S. Hecht, A. Tkatchenko, N. Koch, S.-W. Hla
Subtle Fluorination of Conjugated Molecules Enables Stable Nanoscale Assemblies on Metal Surfaces
J. Phys. Chem. 122, 18902 (2018)
doi: 10.1021/acs.jpcc.8b03398
T. Schultz, J. Niederhausen, R. Schlesinger, S. Sadofev, N. Koch
Impact of surface states and bulk doping level on hybrid inorganic/organic semiconductor interface energy levels
J. Appl. Phys. 123, 245501 (2018)
doi: 10.1063/1.5036579
A. Kyndiah, A. Ablat, S. Guyot-Reeb, T. Schultz, F. Zu, N. Koch, P. Amsalem, S. Chiodini, T. Yilmaz Alic, Y. Topal, M. Kus, L. Hirsch, S. Fasquel,M. Abbas
A Multifunctional Interlayer for Solution Processed High Performance Indium Oxide Transistors
Sci. Rep. 8, 10946 (2018)
doi: 10.1038/s41598-018-29220-0
Q. Wang, G. Ligorio, V. Diez-Cabanes, D. Cornil, B. Kobin, J. Hildebrandt, M. V. Nardi, M. Timpel, S. Hecht, J. Cornil, E. J. W. List-Kratochvil, N. Koch
Dynamic Photoswitching of Electron Energy Levels at Hybrid ZnO/Organic Photochromic Molecule Junctions
Adv. Funct. Mater. 2018, 1800716 (2018)
doi: 10.1002/adfm.201800716
P. Amsalem, G. Heimel, N. Koch
Experimental Investigation on Carge Transfer Between Organic Adsorbates and Solid Surfaces
in: K. Wandelt (Ed.)
Encyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry, 44, 50 (2018)
doi: 10.1016/B978-0-12-409547-2.13035-5
S. Park, N. Mutz, T. Schultz, S. Blumstengel, A. Han, A. Aljarb, L.-J. Li, E. J. W. List-Kratochvil, P. Amsalem, N. Koch
Direct determination of monolayer MoS2 and WSe2 exciton binding energies on insulating and metallic substrates
2D Materials 5, 025003 (2018)
doi: 10.1088/2053-1583/aaa4ca
K. Fu, R. Wang, T. Katase, H. Ohta , N. Koch, S. Duhm
Stoichiometric and Oxygen-Deficient VO2 as Versatile Hole Injection Electrode for Organic Semiconductors
ACS Appl. Mater. Interfaces 10, 10552 (2018)
doi: 10.1021/acsami.8b00026
A. D. Jodlowski, C. Roldán-Carmona, G. Grancini, M. Salado, M. Ralaiarisoa, S. Ahmad, N. Koch, L. Camacho, G. de Miguel, M. K. Nazeeruddin
Large guanidinium cation mixed with methylammonium in lead iodide perovskites for 19% efficient solar cells
Nature Energy 2, 972 (2017)
doi: 10.1038/s41560-017-0054-3
O. T. Hofmann, H. Glowatzki, C. Burker, G. M. Rangger, B. Broker, J. Niederhausen, T. Hosokai, I. Salzmann, R. P. Blum, R. Rieger, A. Vollmer, P. Rajput, A. Gerlach, K. Mullen, F. Schreiber, E. Zojer, N. Koch, S. Duhm
Orientation-Dependent Work-Function Modification Using Substituted Pyrene-Based Acceptors
J. Phys. Chem. C Nanomater. Interfaces 121, 24657 (2017)
doi: 10.1021/acs.jpcc.7b08451
F. Zu, P. Amsalem, M. Ralaiarisoa, T. Schultz, R. Schlesinger, N. Koch
Surface State Density Determines the Energy Level Alignment at Hybrid Perovskite/Electron Acceptors Interfaces
ACS Appl. Mater. Interfaces 9, 41546 (2017)
doi: 10.1021/acsami.7b12586
Q. Wang, J. Frisch, M. Herder, S. Hecht, N. Koch
Electronic Properties of Optically Switchable Photochromic Diarylethene Molecules at the Interface with Organic Semiconductors
Chem. Phys. Chem 18, 722 (2017)
doi: 10.1002/cphc.201601442
X. Lin, B. Wegner, K. M. Lee, M. A. Fusella, F. Zhang, K. Moudgil, B. P. Rand, S. Barlow, S. R. Marder, N. Koch, A. Kahn
Beating the thermodynamic limit with photo-activation of n-doping in organic semiconductors
Nature Materials 16, 1209 (2017)
doi: 10.1038/nmat5027
J. Li, S.-C. Dong, A. Opitz, L.-S. Liao, N. Koch
Design principles of carbazole/dibenzothiophene derivatives as host material in modern efficient organic light-emitting diodes
J. Mater. Chem. C 5, 6989 (2017)
doi: 10.1039/C7TC02248D
M. Ralaiarisoa, Y. Busby, J. Frisch, I. Salzmann,J. J. Pireaux, N. Koch
Correlation of annealing time with crystal structure, composition, and electronic properties of CH3NH3PbI3-xClx mixed-halide perovskite films
Phys. Chem. Chem. Phys. 19, 828 (2017)
doi: 10.1039/c6cp06347k
Z. Song, T. Schultz, Z. Ding, B. Lei, C. Han, P. Amsalem, T. Lin, D. Chi, S. L. Wong, Y. J. Zheng, M. Y. Li, L. J. Li, W. Chen, N. Koch, Y. L. Huang, A. T. S. Wee
Electronic Properties of a 1D Intrinsic/p-Doped Heterojunction in a 2D Transition Metal Dichalcogenide Semiconductor
J. Mater. Chem. C 5, 6989 (2017)
doi: 10.1021/acsnano.7b03953
T. Schultz, T. Lenz, N. Kotadiya, G. Heimel, G. Glasser, R. Berger, P. W. M. Blom, P. Amsalem, D. M. de Leeuw, N. Koch
Reliable Work Function Determination of Multicomponent Surfaces and Interfaces: The Role of Electrostatic Potentials in Ultraviolet Photoelectron Spectroscopy
Adv. Mat. Interfaces 4, 1700324 (2017)
doi: 10.1002/admi.201700324
M. Eyer, J. Frisch, S. Sadofev, N. Koch, E. J. W. List-Kratochvil, S. Blumstengel
Role of Hybrid Charge Transfer States in the Charge Generation at ZnMgO/P3HT Heterojunctions
J. Phys. Chem. C 121, 21955 (2017)
doi: 10.1021/acs.jpcc.7b07293
F.-S. Zu, P. Amsalem, I. Salzmann, R.-B. Wang, M. Ralaiarisoa, S. Kowarik, S. Duhm, N. Koch
Impact of White Light Illumination on the Electronic and Chemical Structures of Mixed Halide and Single Crystal Perovskites
Adv. Optical Mater. 5, 1700139 (2017)
doi: 10.1002/adom.201700139
C. M. Wolff, F. Zu, A. Paulke, L. P. Toro, N. Koch, D. Neher
Reduced Interface-Mediated Recombination for High Open-Circuit Voltages in CH3NH3PbI3 Solar Cells
Adv. Mater. 2017, 1700159 (2017)
doi: 10.1002/adma.201700159
J. Niederhausen, H. R. Kersell, C. Christodoulou, G. Heimel, H. Wonneberger, K. Mullen, J. P. Rabe, S. W. Hla, N. Koch
Monolayer Phases of a Dipolar Perylene Derivative on Au(111) and Surface Potential Build-Up in Multilayers
Langmuir 32, 3587 (2016)
doi: 10.1021/acs.langmuir.6b00053
T. Mosciatti, M. G. Del Rosso, M. Herder, J. Frisch, N. Koch, S. Hecht, E. Orgiu, P. Samori
Light-Modulation of the Charge Injection in a Polymer Thin-Film Transistor by Functionalizing the Electrodes with Bistable Photochromic Self-Assembled Monolayers
Adv. Mater. 28, 6606 (2016)
doi: 10.1002/adma.201600651
T. Schultz, R. Schlesinger, J. Niederhausen, F. Henneberger, S. Sadofev, S. Blumstengel, A. Vollmer, F. Bussolotti, J.-P. Yang, S. Kera, K. Parvez, N. Ueno, K. Müllen, N. Koch
Tuning the work function of GaN with organic molecular acceptors
Phys. Rev. B 93, 125309 (2016)
doi: 10.1103/PhysRevB.93.125309
S. Käbisch, M. Timpel, H. Kirmse, M. A. Gluba, N. Koch, N. H. Nickel
Polarity of pulsed laser deposited ZnO nanostructures
Appl. Phys. Lett. 108, 083114 (2016)
doi: 10.1063/1.4942887
I. Salzmann, G. Heimel, M. Oehzelt, S. Winkler, and N. Koch
Molecular Electrical Doping of Organic Semiconductors: Fundamental Mechanisms and Emerging Dopant Design Rules
Acc. Chem. Res., 49 (3) (2016)
doi: 10.1021/acs.accounts.5b00438
R. Schlesinger, F. Bianchi, S. Blumstengel, C. Christodoulou, R. Ovsyannikov, B. Kobin, K. Moudgil, S. Barlow, S. Hecht, S. R. Marder, F. Henneberger,and N. Koch
Efficient light emission from inorganic and organic semiconductor hybrid structures by energy-level tuning
Nature Communications 6 (2015)
doi: 10.1038/ncomms7754
M. Timpel, M. V. Nardi, G. Ligorio, B. Wegner, M. Pätzel, B. Kobin, S. Hecht and N. Koch
Energy-Level Engineering at ZnO/Oligophenylene Interfaces with Phosphonate-Based Self-Assembled Monolayers
ACS Appl. Mater. Interfaces 7 (22), 11900 (2015)
doi: 10.1021/acsami.5b01669
H. Méndez, G. Heimel, S. Winkler, J. Frisch, A. Opitz, K. Sauer, B. Wegner, M. Oehzelt, C. Röthel, S. Duhm, D. Többens, N. Koch, I. Salzmann
Charge-transfer crystallites as molecular electrical dopants
Nat. Commun., 6:8560 (2015)
doi: 10.1038/ncomms9560
S. Winkler, P. Amsalem, J. Frisch, M. Oehzelt, G. Heimel, N. Koch
Probing the energy levels in hole-doped molecular semiconductors
Mater. Horiz., 2, 427 (2015)
doi: 10.1039/c5mh00023h
P. Amsalem, G. Heimel, M. Oehzelt, N. Koch
The interface electronic properties of organic photovoltaic cells
Journal of Electron Spectroscopy and Related Phenomena, 204, 177 (2015)
doi: 10.1016/j.elspec.2015.02.012
C. Christodoulou, A. Giannakopoulos, G. Ligorio, M. Oehzelt, M. Timpel, J. Niederhausen, L. Pasquali, A. Giglia, K. Parvez, K. Müllen, D. Beljonne, N. Koch, and M. V. Nardi
Tuning the Electronic Structure of Graphene by Molecular Dopants: Impact of the Substrate
ACS Appl. Mater. Interfaces, 7, 19134 (2015)
doi: 10.1021/acsami.5b04777
S. Yu, J. Frisch, A. Opitz, E. Cohen, M. Bendikov, N. Koch, I. Salzmann
Effect of molecular electrical doping on polyfuran based photovoltaic cells
Appl. Phys. Lett. 106, 203301 (2015)
doi: 10.1063/1.4921484
M. Oehzelt, K. Akaike, N. Koch, G. Heimel
Energy-level alignment at organic heterointerfaces
Sci. Adv. 1, e1501127 (2015)
doi: 10.1126/sciadv.1501127
K. Akaike, N. Koch, G. Heimel, M. Oehzelt
The Impact of Disorder on the Energy Level Alignment at Molecular Donor-Acceptor Interfaces
Adv. Master Interfaces, 2, 1500232 (2015)
doi: 10.1002/admi.201500232
F. Piersimoni, R. Schlesinger, J. Benduhn, D. Spoltore, S. Reiter, I. Lange, N. Koch, K. Vandewal, D. Neher
Charge Transfer Absorption and Emission at ZnO/Organic Interfaces
J. Phys. Chem. Lett. 6, 500 (2015)
doi: 10.1021/jz502657z
S. Winkler, J. Frisch, R. Schlesinger, M. Oehzelt, R. Rieger, J. Räder, J. P. Rabe, K. Müllen, N. Koch
Impact of molecular dipole moments on Fermi level pinning in thin films
J. Phys. Chem. C 118, 11731 (2014)
doi:10.1021/jp5021615
H. Wang, P. Amsalem, G. Heimel, I. Salzmann, N. Koch, M. Oehzelt
Band-bending in organic semiconductors: The role of alkali-halide interlayers
Adv. Mater. 26, 925 (2014)
doi:10.1002/adma.201303467
M. Timpel, M. V. Nardi, S. Krause, G. Ligorio, C. Christodoulou, L. Pasquali, A. Giglia, J. Frisch, B. Wegner, P. Moras, N. Koch
Surface modification of ZnO(0001)−Zn with phosphonate-based self-assembled monolayers: Binding modes, orientation, and work function
Chem. Mater. 26, 5042-5050 (2014)
doi:10.1021/cm502171m
J. Niederhausen, S. Duhm, G. Heimel, C. Bürker, Q. Xin, A. Wilke, A. Vollmer, F. Schreiber, S. Kera, J.P. Rabe, N. Ueno, N. Koch
Seleno groups control the energy-level alignment between conjugated organic molecules and metals
J. Chem. Phys. 140, 014705 (2014)
doi: 10.1063/1.4858856
M. Oehzelt, N. Koch, G. Heimel
Organic semiconductor density of states controls the energy level alignment at electrode interfaces
Nature Comm. 5, 4174 (2014)
doi:10.1038/ncomms5174
S. Winkler, J. Frisch, R. Schlesinger, M. Oehzelt, R. Rieger, J. Räder, J.P. Rabe, K. Müllen, N. Koch
The impact of local work function variations on Fermi level pinning of organic semiconductors
J. Phys. Chem. C 117 (2013) 22285-22289.
doi: 10.1021/jp401919z
R. Schlesinger, Y. Xu, O. T. Hofmann, S. Winkler, J. Frisch, J. Niederhausen, A. Vollmer, S. Blumstengel, F. Henneberger, P. Rinke, M. Scheffler, N. Koch
Controlling the work function of ZnO and the energy-level alignment at the interface to organic semiconductors with a molecular electron acceptor
Physical Review B 87, 155311 (2013)
doi:10.1103/PhysRevB.87.155311
P. Amsalem, J. Niederhausen, A. Wilke, G. Heimel, R. Schlesinger, S. Winkler, A. Vollmer, J.P. Rabe, N. Koch
Role of charge transfer, dipole-dipole interactions, and electrostatics in Fermi-level pinning at a molecular heterojunction on a metal surface
Phys. Rev. B 87 (2013) 035440.
doi: 10.1103/PhysRevB.87.035440
Y. Xu, O. T. Hofmann, R. Schlesinger, S. Winkler, J. Frisch, J. Niederhausen, A. Vollmer, S. Blumstengel, F. Henneberger, N. Koch, P. Rinke, M. Scheffler
Space Charge Transfer in Hybrid Inorganic/Organic Systems
Phys. Rev. Lett. 111, 226802 (2013)
doi:10.1103/PhysRevLett.111.226802
J. Niederhausen, P. Amsalem, A. Wilke, R. Schlesiger, S. Winkler, A. Vollmer, J.P. Rabe, N. Koch
Doping of C60 (sub)-monolayers by Fermi-level pinning induced electron transfer
Phys. Rev. B 86 (2012) 081411(R).
doi:10.1103/PhysRevB.86.081411

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